Stadio Diego Armando Maradona | Champions League 2026-27 | Wednesday, September 9 | 8pm BST
Hoping to go one better than last year, BetVictor News takes a closer look at the Napoli vs Arsenal odds – providing a detailed match preview, score prediction, overall H2H record, team news, the best betting angles and more.
- Napoli vs Arsenal prediction: Gunner glory in Naples
- Bet on the Champions League with BetVictor
Napoli Vs Arsenal Odds
Although the pain of Gabriel’s penalty miss is still fresh, the Napoli vs Arsenal Champions League odds strongly imply a win for the Gunners is on the cards in Naples. The Premier League champions can be backed at 8/11, the draw is online at 27/10 with Gli Azzurri priced at 18/5.
Ahead of the game, the most popular Napoli vs Arsenal betting markets are online which include BTTS, O/U, anytime goalscorers, bet builders, bet boosts, correct score, Asian lines and many, many more.
Napoli Vs Arsenal Preview
After beating Genoa in their Serie A opener, Napoli have felt the wrath of Cesc Fabregas’ Como and suffered a late collapse at Inter Milan on Sunday. Head coach Max Allegri is already feeling the heat and is in desperate need of a win to keep supporters onside.
On Sunday, Arsenal’s 2-1 win over Chelsea means the Gunners have won three out of three so far in 2026-27. In the UCL, Mikel Arteta has led his side to the quarter-final, semi-final and last year’s finale. Will this term be fourth time lucky for the Spaniard?
Napoli Vs Arsenal H2H Record
Napoli have faced Arsenal four times in European competition with the Gunners boasting three wins. The Serie A side’s only victory came in the 2013-14 UCL group stages whereby Gonzalo Higuain and Jose Callejon netted in a 2-0 win in Naples.
Napoli vs Arsenal H2H record:
- Napoli 0-1 Arsenal – 2018-19 (UEL)
- Arsenal 2-0 Napoli – 2018-19 (UEL)
- Napoli 2-0 Arsenal – 2013-14 (UCL)
- Arsenal 2-0 Napoli – 2013-14 (UCL)
Napoli Vs Arsenal Team News
Man City legend Kevin De Bruyne is pushing to start on Wednesday night but the likes of Alessandro Buongiorno, Luca Marianucci and Giovane are ruled out. So to is 2024-25 Serie A Player of the Year Scott McTominay who is set to miss the next four weeks of action.
Meanwhile, Arsenal aren’t expected to make too many changes to their starting XI from the one that beat Chelsea on Sunday. Cristhian Mosquera is likely to miss out once again but Martin Zubimendi could make a start in midfield alongside Declan Rice.
Napoli’s form in 2026-27:
WLL
Arsenal’s form in 2026-27:
WWW
Napoli Vs Arsenal Predicted Lineups
Napoli predicted lineup:
Meret; Di Lorenzo, Marin, Rrahmani, Spinazzola; De Bruyne, Lobotka, Anguissa; Politano, Hojlund, Santos
Arsenal predicted lineup:
Raya; White, Konsa, Gabriel, Hincapie; Zubimendi, Rice; Saka, Odegaard, Tzolis; Havertz
Napoli Vs Arsenal TV Channel, Live Streaming And Radio
Napoli vs Arsenal is available to watch live in the UK on TNT Sports 2 and TNT Sports Ultimate. Live streaming is available via Discovery+, HBO Max app or a HBO Max sports pass. Viewers can also tune in via Sky Go and Virgin TV Go with a TNT Sports add-on. Kick-off is 8pm BST. For those looking to tune in via radio, talkSPORT 2 has you covered.
*A valid TV license and TNT Sports subscription is required to watch live in the UK
Napoli Vs Arsenal Betting Angles
Key Match Stats
- Champions League stats – This will be just the third UCL meeting between the sides.
- Napoli stats – Gli Azzurri have scored in 23 of their last 24 UCL home games.
- Arsenal stats – The Gunners kept the most clean sheets in the UCL last season (9) and conceded the least (7).
Top Betting Angles for Napoli Vs Arsenal
- Under 2.5 goals: Arsenal’s last seven UCL matches produced under 2.5 goals. Online at 17/20.
- BTTS (No): In the four previous H2H clashes, BTTS (no) has come in every time. Our football betting markets have BTTS (no) available at 9/10.
- Anytime goalscorers: Kai Havertz (7/5), Bukayo Saka (11/5), Viktor Gyokeres (8/5) and Christos Tzolis (2/1) are all worth considering.
Napoli Vs Arsenal Prediction
Napoli can be tough opponents to navigate at the Maradona Stadium in the Champions League but owing to their recent form in Serie A – coupled with Arsenal getting into their stride – we are going to predict a low scoring win for the Gunners.
Prediction: Napoli 0-2 Arsenal
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Any betting decisions should be made responsibly and there are no guarantees when it comes to match outcomes. All odds correct as of 4pm on September 7, 2026 and are subject to change.
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